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Pokémon Aesthetic Red: The start (before Brock)

What opens up at this point in the game, and everything you can catch by now that you couldn't before.

Now usable

Tall grass or a cave floor
Surf
Fish with the Old Rod
Fish with the middle rod
Fish with the Super Rod
Smash rocks
A scripted encounter or gift
An in-game trade
Roams after a story trigger
A secret / undocumented encounter
Fossils

Newly reachable

Newly catchable (175)

Mew

TMs you can now pick up

TM01 Focus Punch — Celadon Dept. Store, F3 — TM Move Shop
TM02 Dragon Claw — Celadon Dept. Store, F3 — TM Move Shop
TM03 Water Pulse — Celadon Dept. Store, F3 — TM Move Shop
TM04 Calm Mind — Celadon Dept. Store, F3 — TM Move Shop
TM05 Roar — Celadon Dept. Store, F3 — TM Move Shop
TM06 Toxic — Celadon Dept. Store, F3 — TM Move Shop
TM07 Hail — Celadon Dept. Store, F3 — TM Move Shop
TM08 Bulk Up — Celadon Dept. Store, F3 — TM Move Shop
TM09 Bullet Seed — Celadon Dept. Store, F3 — TM Move Shop
TM10 Hidden Power — Celadon Dept. Store, F3 — TM Move Shop
TM11 Sunny Day — Celadon Dept. Store, F3 — TM Move Shop
TM12 Taunt — Celadon Dept. Store, F3 — TM Move Shop
TM13 Ice Beam — Celadon Dept. Store, F3 — TM Move Shop
TM14 Blizzard — Celadon Dept. Store, F3 — TM Move Shop
TM15 Hyper Beam — Celadon Dept. Store, F3 — TM Move Shop
TM16 Light Screen — Celadon Dept. Store, F3 — TM Move Shop
TM17 Protect — Celadon Dept. Store, F3 — TM Move Shop
TM18 Rain Dance — Celadon Dept. Store, F3 — TM Move Shop
TM19 Giga Drain — Celadon Dept. Store, F3 — TM Move Shop
TM20 Safeguard — Celadon Dept. Store, F3 — TM Move Shop
TM21 Frustration — Celadon Dept. Store, F3 — TM Move Shop
TM22 Solar Beam — Celadon Dept. Store, F3 — TM Move Shop
TM23 Iron Tail — Celadon Dept. Store, F3 — TM Move Shop
TM24 Thunderbolt — Celadon Dept. Store, F3 — TM Move Shop
TM25 Thunder — Celadon Dept. Store, F3 — TM Move Shop
TM26 Earthquake — Celadon Dept. Store, F3 — TM Move Shop
TM27 Return — Celadon Dept. Store, F3 — TM Move Shop
TM28 Dig — Celadon Dept. Store, F3 — TM Move Shop
TM29 Psychic — Celadon Dept. Store, F3 — TM Move Shop
TM30 Shadow Ball — Celadon Dept. Store, F3 — TM Move Shop
TM31 Brick Break — Celadon Dept. Store, F3 — TM Move Shop
TM32 Double Team — Celadon Dept. Store, F3 — TM Move Shop
TM33 Reflect — Celadon Dept. Store, F3 — TM Move Shop
TM34 Shock Wave — Celadon Dept. Store, F3 — TM Move Shop
TM35 Flamethrower — Celadon Dept. Store, F3 — TM Move Shop
TM36 Sludge Bomb — Celadon Dept. Store, F3 — TM Move Shop
TM37 Sandstorm — Celadon Dept. Store, F3 — TM Move Shop
TM38 Fire Blast — Celadon Dept. Store, F3 — TM Move Shop
TM39 Rock Tomb — Celadon Dept. Store, F3 — TM Move Shop
TM40 Aerial Ace — Celadon Dept. Store, F3 — TM Move Shop
TM41 Torment — Celadon Dept. Store, F3 — TM Move Shop
TM42 Facade — Celadon Dept. Store, F3 — TM Move Shop
TM43 Secret Power — Celadon Dept. Store, F3 — TM Move Shop
TM44 Rest — Celadon Dept. Store, F3 — TM Move Shop
TM45 Attract — Celadon Dept. Store, F3 — TM Move Shop
TM46 Thief — Celadon Dept. Store, F3 — TM Move Shop
TM47 Steel Wing — Celadon Dept. Store, F3 — TM Move Shop
TM48 Skill Swap — Celadon Dept. Store, F3 — TM Move Shop
TM49 Leech Life — Celadon Dept. Store, F3 — TM Move Shop
TM50 Overheat — Celadon Dept. Store, F3 — TM Move Shop
TM51 Roost — Celadon Dept. Store, F3 — TM Move Shop
TM52 Focus Blast — Celadon Dept. Store, F3 — TM Move Shop
TM53 Energy Ball — Celadon Dept. Store, F3 — TM Move Shop
TM54 False Swipe — Celadon Dept. Store, F3 — TM Move Shop
TM55 Brine — Celadon Dept. Store, F3 — TM Move Shop
TM56 Hone Claws — Celadon Dept. Store, F3 — TM Move Shop
TM57 Charge Beam — Celadon Dept. Store, F3 — TM Move Shop
TM58 Endure — Celadon Dept. Store, F3 — TM Move Shop
TM59 Dragon Pulse — Celadon Dept. Store, F3 — TM Move Shop
TM60 Drain Punch — Celadon Dept. Store, F3 — TM Move Shop
TM61 Will-O-Wisp — Celadon Dept. Store, F3 — TM Move Shop
TM62 Silver Wind — Celadon Dept. Store, F3 — TM Move Shop
TM63 Venoshock — Celadon Dept. Store, F3 — TM Move Shop
TM64 Explosion — Celadon Dept. Store, F3 — TM Move Shop
TM65 Shadow Claw — Celadon Dept. Store, F3 — TM Move Shop
TM66 Payback — Celadon Dept. Store, F3 — TM Move Shop
TM67 Recycle — Celadon Dept. Store, F3 — TM Move Shop
TM68 Giga Impact — Celadon Dept. Store, F3 — TM Move Shop
TM69 Rock Polish — Celadon Dept. Store, F3 — TM Move Shop
TM70 Flash — Celadon Dept. Store, F3 — TM Move Shop
TM71 Stone Edge — Celadon Dept. Store, F3 — TM Move Shop
TM72 Avalanche — Celadon Dept. Store, F3 — TM Move Shop
TM73 Thunder Wave — Celadon Dept. Store, F3 — TM Move Shop
TM74 Gyro Ball — Celadon Dept. Store, F3 — TM Move Shop
TM75 Swords Dance — Celadon Dept. Store, F3 — TM Move Shop
TM76 Stealth Rock — Celadon Dept. Store, F3 — TM Move Shop
TM77 Flame Charge — Celadon Dept. Store, F3 — TM Move Shop
TM78 Low Sweep — Celadon Dept. Store, F3 — TM Move Shop
TM79 Dark Pulse — Celadon Dept. Store, F3 — TM Move Shop
TM80 Rock Slide — Celadon Dept. Store, F3 — TM Move Shop
TM81 X-Scissor — Celadon Dept. Store, F3 — TM Move Shop
TM82 Sleep Talk — Celadon Dept. Store, F3 — TM Move Shop
TM83 Scald — Celadon Dept. Store, F3 — TM Move Shop
TM84 Poison Jab — Celadon Dept. Store, F3 — TM Move Shop
TM85 Dream Eater — Celadon Dept. Store, F3 — TM Move Shop
TM86 Grass Knot — Celadon Dept. Store, F3 — TM Move Shop
TM87 Swagger — Celadon Dept. Store, F3 — TM Move Shop
TM88 Pluck — Celadon Dept. Store, F3 — TM Move Shop
TM89 U-turn — Celadon Dept. Store, F3 — TM Move Shop
TM90 Substitute — Celadon Dept. Store, F3 — TM Move Shop
TM91 Flash Cannon — Celadon Dept. Store, F3 — TM Move Shop
TM92 Volt Switch — Celadon Dept. Store, F3 — TM Move Shop
TM93 Dragon Tail — Celadon Dept. Store, F3 — TM Move Shop
TM94 Incinerate — Celadon Dept. Store, F3 — TM Move Shop
TM95 Struggle Bug — Celadon Dept. Store, F3 — TM Move Shop
TM96 Bulldoze — Celadon Dept. Store, F3 — TM Move Shop
TM97 Frost Breath — Celadon Dept. Store, F3 — TM Move Shop
TM98 Work Up — Celadon Dept. Store, F3 — TM Move Shop
TM99 Wild Charge — Celadon Dept. Store, F3 — TM Move Shop
TM100 Infestation — Celadon Dept. Store, F3 — TM Move Shop
TM101 Power-Up Punch — Celadon Dept. Store, F3 — TM Move Shop
TM102 Dazzling Gleam — Celadon Dept. Store, F3 — TM Move Shop
TM103 Sludge Wave — Celadon Dept. Store, F3 — TM Move Shop
TM104 Psyshock — Celadon Dept. Store, F3 — TM Move Shop
TM105 Brutal Swing — Celadon Dept. Store, F3 — TM Move Shop
TM106 Smart Strike — Celadon Dept. Store, F3 — TM Move Shop
TM107 Acrobatics — Celadon Dept. Store, F3 — TM Move Shop
TM108 Snarl — Celadon Dept. Store, F3 — TM Move Shop
TM109 Defog — Celadon Dept. Store, F3 — TM Move Shop
TM110 Captivate — Celadon Dept. Store, F3 — TM Move Shop
TM111 Smack Down — Celadon Dept. Store, F3 — TM Move Shop
TM112 Round — Celadon Dept. Store, F3 — TM Move Shop
TM113 Echoed Voice — Celadon Dept. Store, F3 — TM Move Shop
TM114 Natural Gift — Celadon Dept. Store, F3 — TM Move Shop
TM115 Quash — Celadon Dept. Store, F3 — TM Move Shop
TM116 Trick Room — Celadon Dept. Store, F3 — TM Move Shop
TM117 Fling — Celadon Dept. Store, F3 — TM Move Shop
TM118 Aurora Veil — Celadon Dept. Store, F3 — TM Move Shop
TM119 Sky Drop — Celadon Dept. Store, F3 — TM Move Shop
TM120 Nature Power — Celadon Dept. Store, F3 — TM Move Shop
HM01 Cut — Given by Professor Oak at the start of the game
HM02 Fly — Given by Professor Oak at the start of the game
HM03 Surf — Given by Professor Oak at the start of the game
HM04 Strength — Given by Professor Oak at the start of the game
HM05 Dive — Given by Professor Oak at the start of the game
HM06 Rock Smash — Given by Professor Oak at the start of the game
HM07 Waterfall — Given by Professor Oak at the start of the game
HM08 Rock Climb — Given by Professor Oak at the start of the game

Bosses around here

Brock — Lv 14 Rival — starter pick — Lv 5 Rival — after 0 badges — Lv 12 Brock — Lv 14 Rival — starter pick — Lv 5 Rival — after 0 badges — Lv 12