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Unbound: Starting out — around Lv 5

What opens up at this point in the game, and everything you can catch by now that you couldn't before.

Now usable

Walk in grass
Grass — daytime
Grass — night
Surf — Surf (HM03)
Rock Smash — Rock Smash (HM06)
Fish with the Old Rod — the Old Rod
Fish with the Good Rod — the Good Rod
Fish with the Super Rod — the Super Rod

Newly reachable

Antisis City Antisis Sewers North Antisis Sewers Room Antisis Sewers South Auburn Waterway A Auburn Waterway B Autl Woods East Autl Woods West Cinder Volcano 2F Cinder Volcano 3F 1 Cinder Volcano 4F 2 Cinder Volcano F1 Cinder Volcano Shadow 1F Cinder Volcano Shadow B1F Cinder Volcano Shadow B2F Cinder Volcano Shadow Storage 1 Cinder Volcano Shadow Storage 2 Cliff Cave 1F Cliff Cave 2F Cliff Cave 3F Cootes Bog Crystal Peak 1F Left Room Crystal Peak 1F Main Room Crystal Peak 3F Crystal Peak 5F Crystal Peak B1F Left Crystal Peak Bog Entrance Crystal Peak Cliffside Crystal Peak Cube Entrance Cube Corp Dehara City Distortion World 1 Distortion World 2 Distortion World 3 Dresco Town Epidimy Town Fallshore City Flower Paradise A Flower Paradise B Flower Paradise C Frost Mountain 1F Frost Mountain 2F Frost Mountain 3F Frozen Forest Great Desert A Great Desert B Great Desert C Grim Woods Gurun Town Icicle Cave 1F Icicle Cave 1F Back Icicle Cave B1F Icicle Cave B2F Icicle Cave B3F Icicle Cave B3F Alt Icicle Cave B4F Icicle Cave Clearing Icy Hole 1F Icy Hole B1F Lost Tunnel B1F Magnolia Fields Polder Town Redwood Forest Redwood Village Rift Cave B1F Route 1 Route 10 Route 11 Route 12 Route 13 A Route 13 B Route 14 A Route 14 B Route 14 C Route 15 Route 16 Route 17 Route 18 A Route 18 B Route 2 Route 3 Route 4 Route 5 Route 6 Route 7 Route 8 Route 9 Rov Post Game Aklove Ruins Of Void B3F Ruins Of Void B3F Alt Ruins Of Void Ext Seaport City Tarmigan Town Tehl Town Thundercap Mt 1F Thundercap Mt 2F Thundercap Mt 3F 1 Thundercap Mt 3F 1 Back Thundercap Mt 3F 2 Thundercap Mt 3F 3 Thundercap Mt 4F 2 Thundercap Mt Ext Tomb Of Borrius 1F Tomb Of Borrius 1F Back Tomb Of Borrius B3F Underwater Route 17 Valley Cave A Valley Cave B Valley Cave C Valley Cave D Victory Road Cave A Victory Road Cave B Victory Road Cave C Victory Road Cave D Victory Road Grassy Victory Road Ice Cave A Victory Road Ice Cave B Victory Road Mountainside Victory Road Volcano Vivill Town Vivill Warehouse Research Room Vivill Woods

Newly catchable (353)

Muk

Pumpkaboo (Super Size)

TMs you can now pick up

TM01 Focus Punch — Location not documented — see the hack's location guide
TM02 Dragon Claw — Location not documented — see the hack's location guide
TM03 Water Pulse — Location not documented — see the hack's location guide
TM04 Calm Mind — Location not documented — see the hack's location guide
TM05 Roar — Location not documented — see the hack's location guide
TM06 Toxic — Location not documented — see the hack's location guide
TM07 Hail — Location not documented — see the hack's location guide
TM08 Bulk Up — Location not documented — see the hack's location guide
TM09 Bullet Seed — Location not documented — see the hack's location guide
TM10 Hidden Power — Location not documented — see the hack's location guide
TM11 Sunny Day — Location not documented — see the hack's location guide
TM12 Taunt — Location not documented — see the hack's location guide
TM13 Ice Beam — Location not documented — see the hack's location guide
TM14 Blizzard — Location not documented — see the hack's location guide
TM15 Hyper Beam — Location not documented — see the hack's location guide
TM16 Light Screen — Location not documented — see the hack's location guide
TM17 Protect — Location not documented — see the hack's location guide
TM18 Rain Dance — Location not documented — see the hack's location guide
TM19 Giga Drain — Location not documented — see the hack's location guide
TM20 Safeguard — Location not documented — see the hack's location guide
TM21 Frustration — Location not documented — see the hack's location guide
TM22 Solar Beam — Location not documented — see the hack's location guide
TM23 Iron Tail — Location not documented — see the hack's location guide
TM24 Thunderbolt — Location not documented — see the hack's location guide
TM25 Thunder — Location not documented — see the hack's location guide
TM26 Earthquake — Location not documented — see the hack's location guide
TM27 Return — Location not documented — see the hack's location guide
TM28 Dig — Location not documented — see the hack's location guide
TM29 Psychic — Location not documented — see the hack's location guide
TM30 Shadow Ball — Location not documented — see the hack's location guide
TM31 Brick Break — Location not documented — see the hack's location guide
TM32 Double Team — Location not documented — see the hack's location guide
TM33 Reflect — Location not documented — see the hack's location guide
TM34 Shock Wave — Location not documented — see the hack's location guide
TM35 Flamethrower — Location not documented — see the hack's location guide
TM36 Sludge Bomb — Location not documented — see the hack's location guide
TM37 Sandstorm — Location not documented — see the hack's location guide
TM38 Fire Blast — Location not documented — see the hack's location guide
TM39 Rock Tomb — Location not documented — see the hack's location guide
TM40 Aerial Ace — Location not documented — see the hack's location guide
TM41 Torment — Location not documented — see the hack's location guide
TM42 Facade — Location not documented — see the hack's location guide
TM43 Secret Power — Location not documented — see the hack's location guide
TM44 Rest — Location not documented — see the hack's location guide
TM45 Attract — Location not documented — see the hack's location guide
TM46 Thief — Location not documented — see the hack's location guide
TM47 Steel Wing — Location not documented — see the hack's location guide
TM48 Skill Swap — Location not documented — see the hack's location guide
TM49 Leech Fang — Location not documented — see the hack's location guide
TM50 Overheat — Location not documented — see the hack's location guide
TM51 Roost — Location not documented — see the hack's location guide
TM52 Focus Blast — Location not documented — see the hack's location guide
TM53 Energy Ball — Location not documented — see the hack's location guide
TM54 False Swipe — Location not documented — see the hack's location guide
TM55 Brine — Location not documented — see the hack's location guide
TM56 Hone Claws — Location not documented — see the hack's location guide
TM57 Charge Beam — Location not documented — see the hack's location guide
TM58 Endure — Location not documented — see the hack's location guide
TM59 Dragon Pulse — Location not documented — see the hack's location guide
TM60 Drain Punch — Location not documented — see the hack's location guide
TM61 Will-O-Wisp — Location not documented — see the hack's location guide
TM62 Silver Wind — Location not documented — see the hack's location guide
TM63 Venoshock — Location not documented — see the hack's location guide
TM64 Explosion — Location not documented — see the hack's location guide
TM65 Shadow Claw — Location not documented — see the hack's location guide
TM66 Payback — Location not documented — see the hack's location guide
TM67 Recycle — Location not documented — see the hack's location guide
TM68 Giga Impact — Location not documented — see the hack's location guide
TM69 Rock Polish — Location not documented — see the hack's location guide
TM70 Flash — Location not documented — see the hack's location guide
TM71 Stone Edge — Location not documented — see the hack's location guide
TM72 Avalanche — Location not documented — see the hack's location guide
TM73 Thunder Wave — Location not documented — see the hack's location guide
TM74 Gyro Ball — Location not documented — see the hack's location guide
TM75 Swords Dance — Location not documented — see the hack's location guide
TM76 Stealth Rock — Location not documented — see the hack's location guide
TM77 Flame Charge — Location not documented — see the hack's location guide
TM78 Low Sweep — Location not documented — see the hack's location guide
TM79 Dark Pulse — Location not documented — see the hack's location guide
TM80 Rock Slide — Location not documented — see the hack's location guide
TM81 X-Scissor — Location not documented — see the hack's location guide
TM82 Sleep Talk — Location not documented — see the hack's location guide
TM83 Scald — Location not documented — see the hack's location guide
TM84 Poison Jab — Location not documented — see the hack's location guide
TM85 Dream Eater — Location not documented — see the hack's location guide
TM86 Grass Knot — Location not documented — see the hack's location guide
TM87 Swagger — Location not documented — see the hack's location guide
TM88 Pluck — Location not documented — see the hack's location guide
TM89 U-turn — Location not documented — see the hack's location guide
TM90 Substitute — Location not documented — see the hack's location guide
TM91 Flash Cannon — Location not documented — see the hack's location guide
TM92 Volt Switch — Location not documented — see the hack's location guide
TM93 Dragon Tail — Location not documented — see the hack's location guide
TM94 Incinerate — Location not documented — see the hack's location guide
TM95 Struggle Bug — Location not documented — see the hack's location guide
TM96 Bulldoze — Location not documented — see the hack's location guide
TM97 Frost Breath — Location not documented — see the hack's location guide
TM98 Work Up — Location not documented — see the hack's location guide
TM99 Wild Charge — Location not documented — see the hack's location guide
TM100 Power-Up Hit — Location not documented — see the hack's location guide
TM101 1000 Arrows — Location not documented — see the hack's location guide
TM102 Dazzle Gleam — Location not documented — see the hack's location guide
TM103 Sludge Wave — Location not documented — see the hack's location guide
TM104 Psyshock — Location not documented — see the hack's location guide
TM105 Burn Up — Location not documented — see the hack's location guide
TM106 Sparkle Aria — Location not documented — see the hack's location guide
TM107 Acrobatics — Location not documented — see the hack's location guide
TM108 Snarl — Location not documented — see the hack's location guide
TM109 Defog — Location not documented — see the hack's location guide
TM110 Drain Kiss — Location not documented — see the hack's location guide
TM111 Smack Down — Location not documented — see the hack's location guide
TM112 Round — Location not documented — see the hack's location guide
TM113 Echoed Voice — Location not documented — see the hack's location guide
TM114 Natural Gift — Location not documented — see the hack's location guide
TM115 Double Iron — Location not documented — see the hack's location guide
TM116 Wonder Room — Location not documented — see the hack's location guide
TM117 Gravity — Location not documented — see the hack's location guide
TM118 Baneful Bunk — Location not documented — see the hack's location guide
TM119 Hold Hands — Location not documented — see the hack's location guide
TM120 Nature Power — Location not documented — see the hack's location guide
HM01 Cut — Location not documented — see the hack's location guide
HM02 Fly — Location not documented — see the hack's location guide
HM03 Surf — Location not documented — see the hack's location guide
HM04 Strength — Location not documented — see the hack's location guide
HM05 Dive — Location not documented — see the hack's location guide
HM06 Rock Smash — Location not documented — see the hack's location guide
HM07 Waterfall — Location not documented — see the hack's location guide
HM08 Rock Climb — Location not documented — see the hack's location guide

Next: Around Lv 10 →