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Part 4: World 4 — Main Street Casino: Power Star 4 (Waluigi)

World 4-1 and 4-2, Glittering Cave and the Main Street Casino. Teams here are the World-3-first versions unless you switch the order setting.

World 4 — Main Street Casino: Power Star 4 (Waluigi) opens 5 areas. There are 41 trainers standing in them. The fights at this checkpoint are Admin Kamek, Koopa King Bowser, Waluigi, and 3 more.

Where to go

  1. World 4-1

    Wild: Shrooblet 30% · Lv —, Sprangler 30% · Lv —, Jabble 15% · Lv —, Porcupuffer 15% · Lv — +3 more

    Trainers:Admin Kamek Lv 23, Purple Coiner Inocybe Lv 24, Purple Coiner Lobster Lv 23, Purple Coiner Cremini Lv 25, Purple Coiner Twins Lv 23, Purple Coiner Oyster Lv 25 +13 more

    Pick up: TM15 Thunder Wave, TM75 Venoshock, Mystic Water (hidden — fountain)

  2. Glittering Cave

    Wild: Bandit 40% · Lv —, Fang 30% · Lv —, Brolder 10% · Lv —, Shy Guy 10% · Lv — +2 more

    Trainers: Hiker Truffle Lv 26, Camper Shimeji Lv 24, Hiker Portabella Lv 26, Hiker Truffle Lv 18, Camper Shimeji Lv 18, Hiker Portabella Lv 20

    Pick up: TM23 Rock Slide, TM58 Payback, Comet Shard (hidden — rock near 2 toads), Comet Shard (hidden — blue rocks in limited vision area), Comet Shard (hidden — blue rocks in limited vision area), Comet Shard (hidden — rock near 2 toads), Comet Shard (hidden — blue rocks in limited vision area), Comet Shard (hidden — blue rocks in limited vision area) +5 more

  3. World 4-2

    Wild: Fuzzy 30% · Lv —, Phanto 30% · Lv —, Ghost Mouse 20% · Lv —, Nipper 10% · Lv — +3 more

    Trainers: Purple Coiner Shiitake Lv 29, Purple Coiner Shiitake Lv 20

    Pick up: TM81 Volt Switch, Big Nugget (hidden — south, past the bridge in the middle of wild grass), Sticky Barb (hidden — yellow block)

  4. Glittering Cave (Secret Rooms)

    Wild: Iron Cleft 30% · Lv —, Mr. I 30% · Lv —, Brolder 20% · Lv —, Phanto 10% · Lv —

  5. Main Street Casino

    Wild: Chill Virus Lv —, Fever Virus Lv —, Lil Sparky Lv —, Mechakoopa Lv — +3 more

    Trainers: Purple Coiner Psilocybe Lv 27, ★ Koopa King Bowser Lv 31, Purple Coiner Pluteus Lv 26, Purple Coiner Conocybe Lv 28, Purple Coiner Gymnopilus Lv 28, ★ Waluigi Lv 32 +8 more

    Pick up: TM11 Magical Leaf, TM43 Revenge, TM48 Fake Tears, TM50 Struggle Bug, TM56 Brine, TM61 Power Swap, TM62 Guard Swap, TM63 Speed Swap +2 more

★ Admin Kamek — World 4-1

1 Pokémon · level cap Lv 23 (every cap) · Admin Kamek’s own page

PokémonMoves
MagikoopaMagikoopa
Lv 23 · Prankster
Confusion Gust Tri Attack Block

★ Koopa King Bowser — Main Street Casino

4 Pokémon · level cap Lv 31 (every cap) · Koopa King Bowser’s own page

PokémonMoves
Chain ChompChain Chomp
Lv 28 · Intimidate
Impish nature · IVs 11 HP / 2 Atk
Dig Rollout Bite Smart Strike
MechakoopaMechakoopa
Lv 29 · Lightning Rod
Adamant nature · IVs 11 HP / 2 Atk
Gear Grind Selfdestruct Spark Autotomize
MagikoopaMagikoopa
Lv 30 · Magic Guard · Sitrus Berry
Modest nature · IVs 11 HP / 2 Atk
Air Cutter Psybeam Tri Attack Block
BowserBowser
Lv 31 · Shell Armor
Hasty nature · IVs 31 HP / 15 Atk / 15 Def / 15 SpA
Spiky Shield Incinerate Crush Claw

★ Waluigi — Main Street Casino

5 Pokémon · level cap Lv 32 (every cap) · Waluigi’s own page

PokémonMoves
SwoopSwoop
Lv 29 · Inner Focus · Starf Berry
Jolly nature · IVs 8 HP / 6 Atk
Acupressure Baton Pass Aerial Ace Poison Fang
Huff n PuffHuff n Puff
Lv 29 · Neutralizing Gas · Starf Berry
Timid nature · IVs 8 HP / 6 Atk
Substitute Strange Steam Baton Pass Venoshock
TarantoxTarantox
Lv 30 · Corrosion · Starf Berry
Relaxed nature · IVs 26 HP / 7 Atk
Baton Pass Infestation Toxic Thread Poison Fang
PorcupufferPorcupuffer
Lv 31 · Strong Jaw · Starf Berry
Careful nature · IVs 26 HP / 7 Atk
Baneful Bunker Dive Poison Fang Bite
ShrooboidShrooboid
Lv 32 · Corrosion · Starf Berry
Adamant nature · IVs 26 HP / 7 Atk
Revenge Poison Jab Payback Toxic

Also fought around here

Everything you can have caught by this checkpoint · Open the interactive guide

It also doesn't say when Every fishing spot, Nature Reserve open up, so they are in no part above; each has its own route page.