| Aqua Admin Lazuli | Littleroot Coast | 4 | 48 |
| Pokémon Trainer Luka | Petalburg City | 6 | 45 |
| Pokémon Trainer Luka | Petalburg City | 2 | 7 |
| Rival Zenno (Bulbasaur) | Route 103 | 1 | 5 |
| Rival Zenno (Torchic) | Route 103 | 1 | 5 |
| Rival Zenno (Totodile) | Route 103 | 1 | 5 |
| Rival Zinnia (Bulbasaur) | Route 103 | 1 | 5 |
| Rival Zinnia (Torchic) | Route 103 | 1 | 5 |
| Rival Zinnia (Totodile) | Route 103 | 1 | 5 |
| Rival Zenno (Bulbasaur) | Route 104 | 3 | 20 |
| Rival Zenno (Torchic) | Route 104 | 3 | 20 |
| Rival Zenno (Totodile) | Route 104 | 3 | 20 |
| Rival Zinnia (Bulbasaur) | Route 104 | 3 | 20 |
| Rival Zinnia (Torchic) | Route 104 | 3 | 20 |
| Rival Zinnia (Totodile) | Route 104 | 3 | 20 |
| Terra (Hard mode) | Rustboro City Gym | 3 | 16 |
| Renton (Hard mode) | Dewford Town Gym | 4 | 25 |
| Pokémon Trainer Luka | Mauville City | 4 | 30 |
| Den (Hard mode) | Mauville City Gym | 5 | 34 |
| Rival Zenno (Bulbasaur) | Route 110 | 4 | 32 |
| Rival Zenno (Torchic) | Route 110 | 4 | 32 |
| Rival Zenno (Totodile) | Route 110 | 4 | 32 |
| Rival Zinnia (Bulbasaur) | Route 110 | 4 | 32 |
| Rival Zinnia (Torchic) | Route 110 | 4 | 32 |
| Rival Zinnia (Totodile) | Route 110 | 4 | 32 |
| Aqua Admin Alejandro | Slateport City | 2 | 27 |
| Aqua Leader Inae (Hard mode) | Abandoned Ship | 6 | 45 |
| Amaterasu (Hard mode) | Lavaridge Town Gym | 5 | 42 |
| Pokémon Trainer Steven | Meteor Falls | 6 | 78 |
| Magma Admin Netsu | Mt. Chimney | 4 | 33 |
| Magma Leader Magnus (Hard mode) | Mt. Chimney | 5 | 41 |
| Calendula (Hard mode) | Petalburg City Gym | 6 | 45 |
| Taka (Hard mode) | Fortree City Gym | 6 | 50 |
| Aqua Admin Shelly | Route 119 | 2 | 28 |
| Rival Zenno (Bulbasaur) | Route 119 | 4 | 46 |
| Rival Zenno (Torchic) | Route 119 | 4 | 46 |
| Rival Zenno (Totodile) | Route 119 | 4 | 46 |
| Rival Zinnia (Bulbasaur) | Route 119 | 4 | 46 |
| Rival Zinnia (Torchic) | Route 119 | 4 | 46 |
| Rival Zinnia (Totodile) | Route 119 | 4 | 46 |
| Aqua Admin Rob | Aqua Hideout | 4 | 60 |
| Rival Zenno (Bulbasaur) | Lilycove City | 4 | 53 |
| Rival Zenno (Torchic) | Lilycove City | 4 | 53 |
| Rival Zenno (Totodile) | Lilycove City | 4 | 53 |
| Rival Zinnia (Bulbasaur) | Lilycove City | 4 | 53 |
| Rival Zinnia (Torchic) | Lilycove City | 4 | 53 |
| Rival Zinnia (Totodile) | Lilycove City | 4 | 53 |
| Magma Admin Netsu | Magma Hideout | 4 | 53 |
| Magma Leader Maxie | Magma Hideout | 3 | 39 |
| Soul & Luna (Hard mode) | Mossdeep City Gym | 6 | 55 |
| Aqua Admin Shelly | Seafloor Cavern | 2 | 37 |
| Aqua Leader Inae | Seafloor Cavern | 3 | 43 |
| Rio (Hard mode) | Sootopolis City Gym | 6 | 100 |
| Champion Stella (Hard mode, Tailwind team) | Ever Grande City | 6 | 70 |
| Champion Stella (Hard mode, Trick Room team) | Ever Grande City | 6 | 70 |
| Champion Stella (Hard mode, hazards team) | Ever Grande City | 6 | 70 |
| Elite Four Daemon (Hard mode, doubles) | Ever Grande City | 6 | 70 |
| Elite Four Daemon (Hard mode, singles) | Ever Grande City | 6 | 70 |
| Elite Four Phoebe (Hard mode, doubles) | Ever Grande City | 6 | 70 |
| Elite Four Phoebe (Hard mode, singles) | Ever Grande City | 6 | 70 |
| Elite Four Stark (Hard mode, doubles) | Ever Grande City | 6 | 70 |
| Elite Four Stark (Hard mode, singles) | Ever Grande City | 6 | 70 |
| Elite Four Tsubaki (Hard mode, doubles) | Ever Grande City | 6 | 70 |
| Elite Four Tsubaki (Hard mode, singles) | Ever Grande City | 6 | 70 |
| Rival Zenno (Bulbasaur) | Ever Grande City | 6 | 60 |
| Rival Zenno (Bulbasaur) (Hard mode) | Ever Grande City | 6 | 60 |
| Rival Zenno (Torchic) | Ever Grande City | 6 | 60 |
| Rival Zenno (Torchic) (Hard mode) | Ever Grande City | 6 | 60 |
| Rival Zenno (Totodile) | Ever Grande City | 6 | 60 |
| Rival Zenno (Totodile) (Hard mode) | Ever Grande City | 6 | 60 |
| Rival Zinnia (Bulbasaur) | Ever Grande City | 6 | 60 |
| Rival Zinnia (Bulbasaur) (Hard mode) | Ever Grande City | 6 | 60 |
| Rival Zinnia (Torchic) | Ever Grande City | 6 | 60 |
| Rival Zinnia (Torchic) (Hard mode) | Ever Grande City | 6 | 60 |
| Rival Zinnia (Totodile) | Ever Grande City | 6 | 60 |
| Rival Zinnia (Totodile) (Hard mode) | Ever Grande City | 6 | 60 |
| Pokémon Trainer Wally | Victory Road | 5 | 45 |
| Pokémon Trainer Wally | Victory Road | 5 | 48 |