47level cap
This is around World 7 — Comet Observatory: Power Star 7 (Rosalina) in the story — that page lists everything you can have caught by this point.
Types on this team: Psychic ×5Fairy ×2Dark
| Pokémon | Moves | |
|---|---|---|
 | Luma Lv 45 · Synchronize · Eviolite Calm nature · IVs 31 HP / 31 Def / 31 SpA / 31 SpD · EVs 252 HP / 125 Def / 125 SpD | Psychic Wish Teleport Moonblast |
 | Mr. I Lv 45 · Trace Adamant nature · IVs 15 HP / 31 Atk / 31 Def / 15 Spe / 31 SpD · EVs 100 HP / 150 Atk / 75 Def / 50 Spe / 100 SpD | Lash Out Glare Psycho Cut Reflect |
 | Starbag Lv 45 · Good As Gold Relaxed nature · IVs 31 HP / 15 Atk / 31 Def / 15 SpA / 31 SpD · EVs 150 HP / 90 Def / 90 SpA / 90 SpD | Psychic Dark Pulse Will-O-Wisp Ice Beam |
 | Yux Lv 46 · Magic Bounce Brave nature · IVs 15 HP / 31 Atk / 31 Spe / 31 SpA / 31 SpD · EVs 50 HP / 125 Atk / 50 Def / 75 Spe / 125 SpA / 75 SpD | Psycho Cut Moonblast Thunderbolt Shadow Ball |
 | Lubba Lv 47 · Synchronize · Sitrus Berry Calm nature · IVs 31 HP / 31 Def / 31 SpA / 31 SpD · EVs 252 HP / 252 SpD | Moonblast Psychic Calm Mind Wish |